Amir Shabanlo; mina Khorshidi; Abdolmotaleb Seid Mohammadi
Volume 24, Issue 6 , March and April 2018, , Pages 81-93
Abstract
Background & Objectives: The Azo dyes due to presence of aromatic rings in structure are considered major problems into the environment. In this experimental study, the synergistic effect of persulfate and nano zero-valent iron in degradation of Acid Blue 113 in presence of ultrasonic irradiation ...
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Background & Objectives: The Azo dyes due to presence of aromatic rings in structure are considered major problems into the environment. In this experimental study, the synergistic effect of persulfate and nano zero-valent iron in degradation of Acid Blue 113 in presence of ultrasonic irradiation was investigated.
Materials and Methods: The effect of operating parameter such as initial pH, different concentration of S2O82-, nZVI and initial dye using a batch ultrasound reactor at 40 kHz frequency was investigated. After the optimize process, synergistic dye degradation and COD reduction of colored solution was studied. For characterization of the prepared nZVI particle, transmission electron microscope (TEM) image was used.
Results: To remove 99% dye with initial concentration of 50 mg/L, the optimal condition in the end of 30 min of reaction was pH 3, concentration of S2O82- and nZVI 5 mM and 50 mg/L, respectively. In the same of condition with increasing pH to 11 the dye removal efficiency decreased to 17%, respectively. After 120 min of reaction in the optimal condition, the COD reduction was 95%. Synergistic dye degradation in US/S2O82-/Fe0 process was observed 59%. The TEM image of the synthesized nZVI confirmed the nanoscale Creation.
Conclusion: The US/S2O82-/Fe0 combined process due to high synergistic degradation, can be promising process to industrial wastewater treatment.
Abdolmotalleb Seyyed Mohammadi; Ghorban Asgari; MohammadTaghi Samadi; Ali Pour Mohammadi; Ali Faramarzi Govhar
Volume 22, Issue 4 , September and October 2015, , Pages 571-580
Abstract
Background and aim: Humic Acid (HA) is one of the polyelectrolyte compounds which cause many problems in water treatment process. In present study, UV/IO4- as a novel advance oxidation process, was used for removing HA. Material and methods: In present research, a batch reactor in lab scale was used.This ...
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Background and aim: Humic Acid (HA) is one of the polyelectrolyte compounds which cause many problems in water treatment process. In present study, UV/IO4- as a novel advance oxidation process, was used for removing HA. Material and methods: In present research, a batch reactor in lab scale was used.This reactor with useful volume of 2.5 L, made of stainless steel, which equipped with a low pressure Hg vapor lamp. In this study the effect of some parameters including pH, initial HA concentration, IO4- concentration and Fe (0) nanoparticles concentration were investigated. HA concentration was determined using Spectrophotometer at an absorbance wavelength of 254 nm. Results: According to the results, pH 3, periodate concentration 125 mg/L and Fe (0) Nano particles 12.5 mg/L were determined as optimum conditions. Moreover, results indicated that in presence of UV coupled with Periodate removal efficiency of HA increased to 66.08%, and the increase of Fe (0) Nano particles can led to increase HA removal (73.3%). Conclusion: Results show thatthe presence of UV letto increase in the activation of periodate, on the other hands, the presence of Fe (0) Nano particles led to further activation of periodate subsequently cause the increasing HA removal.